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BackSilicon-Based Synthetic Reagents

Gelest, Inc. produces a large variety of Silicon-based synthetic agents, which are used for the selective transformation of functional groups in organic synthesis.  These reagents include those for Peterson olefinations, cyanosilylations, allylations, vinylations, cross-coupling reactions, silyl enol ethers for cross Aldol chemistry and electrophilic substitution of aldehydes and ketones,  silyl ketene acetals for the electrophilic substitution of  esters, various silanes for selective reductions (see Silicon-Based Reducing Agents), saponification of esters, Lewis acid catalysis among others.  A representative list of the synthetic reagents offered by Gelest, Inc. is shown below.  Custom syntheses of related materials are a strength of Gelest, Inc.

Applicable Gelest Brochures:
Biotechnology

Silanes  
SIT8620.0 Trimethylsilyltrifluoromethanesulfonate
SIT8585.0 Trimethylsilyl cyanide
SIT8564.0  Trimethyliodosilane
SIT8430.0 Trimethylbromosilane
SIT8330.0  Triethylsilane
SIC2305.0 Chloromethylsilyltrimethylsilane
SIA0555.0 Allyltrimetylsilane
SIC2462.0 (Cyclohexenyloxy)Trimethylsilane
SIE4904.0 Ethynyltrimethylsilane
SIV9250.0  Vinyltrimethylsilane
SIT8571.2 2-(Trimethylsiloxy)-1,3-Butadiene
SIT8362.0 Trifluoromethyltrimethylsilane
   
Silicones
HMS-991 Polymethylhydrosiloxane – Trimethylsilyl terminated
SIT7900.0 1,3,5,7-Tetravinyl-1,3,5,7-Tetramethylcyclotetrasiloxane
SIT8737.0 1,3,5-Trivinyl-1,3,5-Trimethylcyclotrisiloxane